Abstract
Structural, magnetic, electrical transport, and heat capacity data are reported for single crystals of TlFeSe. This compound crystallizes in a tetragonal structure similar to the ThCrSi structure, but with vacancies in the Fe layer. The vacancies can be ordered or disordered depending on temperature and thermal history. If the vacancies are ordered, the basal plane lattice constant increases from to . Antiferromagnetic order with the Fe spins along the axis occurs below 430 K, as shown by single-crystal neutron diffraction, and the magnetic structure is reported. In addition, for the vacancy-ordered crystal, two other phase transitions are found at K and K. The phase transitions at and are evident in heat capacity, magnetic susceptibility, resistivity data, and lattice parameters, and the unusual temperature dependence of the magnetic order parameter determined from neutron scattering. The phase transitions at and result in significant changes in the magnetic moment per iron, with 1.72(6) observed at 300 K, 2.07(9) at 140 K, 1.90(9) at 115 K, and 1.31(8) for 5 K if the same “block checkerboard” magnetic structure is used at all temperatures. The phase transitions appear to be driven by small changes in the lattice constant, large magnetoelastic coupling, and the localization of carriers with decreasing temperature.
- Received 2 March 2011
- Corrected 15 July 2011
DOI:https://doi.org/10.1103/PhysRevB.83.224510
©2011 American Physical Society
Corrections
15 July 2011