Plasmon Localization and Giant Fields in an Open-Resonator Metasurface forSurface-Enhanced-Raman-Scattering Sensors

Andrey K. Sarychev, Andrey Ivanov, Andrey N. Lagarkov, Ilya Ryzhikov, Konstantin Afanasev, Igor Bykov, Grégory Barbillon, Nikita Bakholdin, Mikhail Mikhailov, Alexander Smyk, Alexander Shurygin, and Alexander Shalygin
Phys. Rev. Applied 17, 044029 – Published 15 April 2022

Abstract

We present metal-dielectric metasurfaces fabricated from metal periodical nanograting deposited on a dielectric substrate. The metasurface consists of a modulated dielectric, which is covered by a thin silver layer. The metasurface operates as an open plasmon resonator. The theory of plasmons excited in the open resonator formed by a metal nanograting is presented. The large local electromagnetic field is predicted for optical frequencies. The excitation of plasmons is experimentally demonstrated in the metasurface designed on a 4-in. Si wafer. The enhancement of the local electric field results in surface-enhanced Raman scattering (SERS). To investigate the SERS effect, the metasurface is covered with a thin layer of the 4-mercaptophenylboronic acid that molecules form covalent bonds with the silver nanolayer. The enhancement of the Raman scattering serves as a proof of concept. We obtain a detection limit of 230 nM for molecules of 4-mercaptophenylboronic acid.

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  • Received 29 October 2021
  • Revised 14 March 2022
  • Accepted 16 March 2022

DOI:https://doi.org/10.1103/PhysRevApplied.17.044029

© 2022 American Physical Society

Physics Subject Headings (PhySH)

Particles & FieldsAtomic, Molecular & OpticalCondensed Matter, Materials & Applied Physics

Authors & Affiliations

Andrey K. Sarychev1,*, Andrey Ivanov1, Andrey N. Lagarkov1, Ilya Ryzhikov1, Konstantin Afanasev1, Igor Bykov1,2, Grégory Barbillon3, Nikita Bakholdin4, Mikhail Mikhailov4, Alexander Smyk5, Alexander Shurygin5, and Alexander Shalygin6

  • 1Institute for Theoretical and Applied Electrodynamics, Russian Academy of Sciences, Moscow 125412, Russia
  • 2Laboratory of Nano-Bioengineering, National Research Nuclear University MEPhI (Moscow Engineering Physics Institute), 31 Kashirskoe shosse, Moscow 115521, Russia
  • 3EPF-Ecole d’Ingénieurs, 55 Avenue du Président Wilson, Cachan 94230, France
  • 4National Research University “Moscow Power Engineering Institute”, Krasnokazarmennaya 14, Moscow 111250, Russia
  • 5James River Branch llc, 8, Tvardovsky st., Strogino Industrial Park, Moscow 123458, Russia
  • 6Lomonosov Moscow State University, Faculty of Physics, GSP-1, 1-2 Leninskiye Gory, Moscow 119991, Russia

  • *sarychev_andrey@yahoo.com

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Vol. 17, Iss. 4 — April 2022

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