Coupling Space-Resolved Dynamic Light Scattering and Rheometry to Investigate Heterogeneous Flow and Nonaffine Dynamics in Glassy and Jammed Soft Matter

A. Pommella, A.-M. Philippe, T. Phou, L. Ramos, and L. Cipelletti
Phys. Rev. Applied 11, 034073 – Published 29 March 2019

Abstract

We present a light-scattering setup coupled to a commercial rheometer operated in the plate-plate geometry. The apparatus allows the microscopic dynamics to be measured, discriminating between the contribution due to laminar flow or affine deformation and additional mechanisms, such as plasticity. Light backscattered by the sample is collected with an imaging optical layout, thereby allowing the average flow velocity and the microscopic dynamics to be probed with both spatial and temporal resolution. We successfully test the setup by measuring the Brownian diffusion and flow velocity of dilute colloidal suspensions, both at rest and under shear. The potentialities of the apparatus are explored in the start-up shear of a biogel. For small shear deformations, γ2%, the rheological response of the gel is linear. However, striking deviations from affine deformation are seen from the very onset of shear, due to temporally and spatially heterogeneous rearrangements having intriguing similarities with a stick-slip process.

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  • Received 3 September 2018
  • Revised 23 January 2019

DOI:https://doi.org/10.1103/PhysRevApplied.11.034073

© 2019 American Physical Society

Physics Subject Headings (PhySH)

Polymers & Soft Matter

Authors & Affiliations

A. Pommella, A.-M. Philippe, T. Phou, L. Ramos, and L. Cipelletti*

  • Laboratoire Charles Coulomb (L2C), UMR 5221 CNRS-Université de Montpellier, Place E. Bataillon F-34095 Montpellier cedex 5, France

  • *luca.cipelletti@umontpellier.fr

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Vol. 11, Iss. 3 — March 2019

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