Illustration of the role of saddle-point and molecular-type ionization mechanisms in atomic collisions

Clara Illescas, I. Rabadán, and A. Riera
Phys. Rev. A 57, 1809 – Published 1 March 1998
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Abstract

We complete a previous description of classical ionization in He2++H collisions, extending the energy range of the illustrations and using as initial conditions either a microcanonical distribution or a hydrogenic one that produces better cross sections near threshold. We call those ionizing electrons that are bound in a frame where the nuclear motion is suppressed molecular-type electrons. We illustrate the evolution of these electrons in phase space, and show that it may properly be called saddle-point ionization at low nuclear velocities, while they give rise at high energies to the standard direct ionization process.

  • Received 9 June 1997

DOI:https://doi.org/10.1103/PhysRevA.57.1809

©1998 American Physical Society

Authors & Affiliations

Clara Illescas1, I. Rabadán2, and A. Riera1

  • 1Departamento de Química, C-IX, Universidad Autónoma de Madrid, Cantoblanco, E-28049 Madrid, Spain
  • 2Department of Physics and Astronomy, University College, London, United Kingdom

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Vol. 57, Iss. 3 — March 1998

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