X-ray reflectivity studies of a microemulsion surface

D. K. Schwartz, A. Braslau, B. Ocko, P. S. Pershan, J. Als-Nielsen, and J. S. Huang
Phys. Rev. A 38, 5817 – Published 1 December 1988
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Abstract

The surface structure of the AOT (sodium di-2-ethylsulfosuccinate) microemulsion system with equal volume fractions of D2O and decane, for AOT volume fractions of 0.42, 0.305, and 0.181, has been studied by a combination of x-ray specular reflectivity and scattering from the bulk. Scattering from the bulk material below the surface is consistent with Kotlarchyk’s interpretation of densely packed spherical micelles. Specular reflectivity from the surface implies a surface electron-density profile consistent with one to two layers of microemulsion droplets. The size of and distance between droplets is consistent with the respective values for the droplets in the bulk phase.

  • Received 28 March 1988

DOI:https://doi.org/10.1103/PhysRevA.38.5817

©1988 American Physical Society

Authors & Affiliations

D. K. Schwartz, A. Braslau, B. Ocko, and P. S. Pershan

  • Division of Applied Physics and Department of Physics, Harvard University, Cambridge, Massachusetts 02138

J. Als-Nielsen

  • Risö National Laboratory, DK-4000 Roskilde, Denmark

J. S. Huang

  • Corporate Research Science Laboratories, Exxon Research and Engineering Company, Annandale, New Jersey 08801

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Issue

Vol. 38, Iss. 11 — December 1988

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