Projection-operator approach to potential scattering

W. Domcke
Phys. Rev. A 28, 2777 – Published 1 November 1983
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Abstract

The projection-operator approach of Feshbach is applied to potential scattering. The aim is to describe single-particle or shape resonances in a mathematically rigorous manner as discrete states interacting with a continuum, in analogy to the well-known description of closed-channel resonances in scattering from targets with internal degrees of freedom. A projection operator Q is defined as Q=Σν=1N|χνχν|, where {r|χν} is an arbitrary orthonormal set of L2 functions. The complementary P space is spanned by a set of scattering states obtained in explicit form by orthogonalizing the free continuum to the set {r|χν}. The free Green's function in P space is constructed explicitly and the P-space scattering problem is solved with the use of separable expansions of the potential. Two standard model problems—s-wave scattering from the square-well potential and the δ-shell potential—are solved exactly, with the use of an arbitrary number of eigenstates of a particle in a spherical box to define the Q space. It is shown that the formalism leads to a decomposition of the exact T matrix and scattering phase shift into an orthogonality scattering, a direct scattering, and a resonant scattering contribution. The pole structure of the corresponding S matrices in the complex momentum plane is analyzed. Finally, the question of how to construct the appropriate discrete state, which projects out a given resonance, is briefly discussed.

  • Received 27 December 1982

DOI:https://doi.org/10.1103/PhysRevA.28.2777

©1983 American Physical Society

Authors & Affiliations

W. Domcke

  • Theoretische Chemie, Physikalisch-Chemisches Institut, Universität Heidelberg, D-6900 Heidelberg, Federal Republic of Germany

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Issue

Vol. 28, Iss. 5 — November 1983

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