Correlation Function Method for the Transport Coefficients of Dense Gases. II. First Density Correction to the Shear Viscosity for Systems with Attractive Forces

Kyozi Kawasaki and Irwin Oppenheim
Phys. Rev. 139, A649 – Published 2 August 1965
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Abstract

Extending the technique presented in our earlier work, the correlation-function expression for the shear viscosity is evaluated up to the first-density correction for a classical system of particles interacting with pair and three-body forces of short range which may have attractive parts and may allow for bound states. The results contain new terms as a result of the existence of bound states, in addition to those obtained for the first-density correction to the shear viscosity for the case of purely repulsive forces. In particular, ηKU, ηUK, and ηUU involve genuine three-body dynamics and give rise to finite contributions to the first-density correction. Diagrams are provided which help to visualize the various processes contributing to the shear viscosity. Finally, higher order density corrections and unstable clusters are briefly discussed.

  • Received 10 March 1965

DOI:https://doi.org/10.1103/PhysRev.139.A649

©1965 American Physical Society

Authors & Affiliations

Kyozi Kawasaki and Irwin Oppenheim

  • Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts

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Issue

Vol. 139, Iss. 3A — August 1965

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