Correlation-Function Method for the Transport Coefficients of Dense Gases. I. First Density Correction to the Shear Viscosity

Kyozi Kawasaki and Irwin Oppenheim
Phys. Rev. 136, A1519 – Published 14 December 1964
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Abstract

The first density correction to the shear viscosity of the classical gas is calculated using the autocorrelation function expression. The technique employed is that due to Zwanzig suitably generalized to include dynamical fluxes containing particle coordinates. If we restrict ourselves to repulsive forces, our result is in complete agreement with that of Choh and Uhlenbeck obtained with the use of Bogolyubov's theory.

  • Received 28 July 1964

DOI:https://doi.org/10.1103/PhysRev.136.A1519

©1964 American Physical Society

Authors & Affiliations

Kyozi Kawasaki and Irwin Oppenheim

  • Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts

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Issue

Vol. 136, Iss. 6A — December 1964

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