Theory of Transport Coefficients for Moderately Dense Gases

M. H. ERNST, L. K. HAINES, and J. R. DORFMAN
Rev. Mod. Phys. 41, 296 – Published 1 April 1969
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Abstract

A general introduction to and bibliography for transport phenomena in gases is provided. Methods for obtaining density expansions of transport coefficients from time-correlation functions in a moderately dense gas with short-range repulsive intermolecular forces are considered. A unified treatment of the two methods appearing in the literature (the t method due to Cohen, Dorfman, and Ernst and the ε method due to Zwanzig) is given. Both of these methods lead to integral equations from which the first two terms in the density expansion of transport coefficients can be computed. However, because of many-body effects in the gas, both methods diverge when used to compute terms beyond the first two in these density expansions. Because of this divergence, it is necessary to prove that the t and ε methods give the same results for the first two terms in the density expansion of transport coefficients. The required proof is provided, and we conclude that either the t or ε method can be used to compute the first two terms in the density expansion of transport coefficients provided one assumes that the remaining (divergent) terms, which are neglected, do not contribute to the first two terms.

    DOI:https://doi.org/10.1103/RevModPhys.41.296

    ©1969 American Physical Society

    Authors & Affiliations

    M. H. ERNST

    • University of Nijmegen, Nijmegen, The Netherlands

    L. K. HAINES*

    • Department of Physics, Amherst College, Amherst, massachusetts

    J. R. DORFMAN

    • Department of Physics and Astronomy and Institute for Fluid Dynamics and Applied Mathematics, University of Maryland, College Park, Maryland

    • *Work supported in part by the National Science Foundation.
    • Work supported in part by the U.S. Army Research Office (Durham) Grant AROD-31-124-G783 and in part by the U.S. Air Force Office of Scientific Research Grant AFOSR-1015-67.

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    Issue

    Vol. 41, Iss. 2 — April - June 1969

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