Abstract
Metallic undergoes a continuous ferroelectric-like structural phase transition below to realize a polar metal. To understand the microscopic interactions that drive this transition, we study its critical behavior above via electromechanical coupling—distortions of the lattice induced by short-range dipole-dipole correlations arising from Li off-center displacements. By mapping the full angular distribution of second harmonic electric-quadrupole radiation from and performing a simplified hyper-polarizable bond model analysis, we uncover subtle symmetry-preserving lattice distortions over a broad temperature range extending from up to around 230 K, characterized by nonuniform changes in the short and long Li-O bond lengths. Such an extended region of critical fluctuations may explain anomalous features reported in specific heat and Raman scattering data and suggests the presence of competing interactions that are not accounted for in existing theoretical treatments. More broadly, our results showcase how electromechanical effects serve as a probe of critical behavior near inversion symmetry-breaking transitions in metals.
2 More- Received 23 January 2020
- Revised 30 April 2020
- Accepted 9 July 2020
DOI:https://doi.org/10.1103/PhysRevResearch.2.033174
Published by the American Physical Society under the terms of the Creative Commons Attribution 4.0 International license. Further distribution of this work must maintain attribution to the author(s) and the published article's title, journal citation, and DOI.
Published by the American Physical Society