Self-Consistent Ornstein-Zernike Approximation for Lattice Gases

Ronald Dickman and George Stell
Phys. Rev. Lett. 77, 996 – Published 5 August 1996
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Abstract

A self-consistent approximation for the structure factor of three-dimensional lattice gases yields remarkably accurate predictions (less than 3% error over most of the temperature range) for the correlation length, isothermal compressibility, specific heat, and the coexistence curve. Critical temperatures agree to within 0.2%, and other critical properties to within (1–2)%, of the best numerical estimates. Until temperature and density are within 1% of their critical values, the approximate effective critical exponents do not differ appreciably from their estimated exact form; they attain their limiting spherical-model values only much closer to critical. The method should prove useful for a variety of three-dimensional lattice-gas and fluid problems; it is inappropriate to two dimensions, where it predicts criticality at zero temperature.

  • Received 1 September 1995

DOI:https://doi.org/10.1103/PhysRevLett.77.996

©1996 American Physical Society

Authors & Affiliations

Ronald Dickman1 and George Stell2

  • 1Department of Physics and Astronomy, Lehman College, CUNY, Bronx, New York 10468-1589
  • 2Department of Chemistry, State University of New York, Stony Brook, New York 11790-3400

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Vol. 77, Iss. 6 — 5 August 1996

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