Structure analysis of a quenched blue phase I using electron microscopy

Hervé Delacroix, Jean-Marc Gilli, Inge Erk, and Paolo Mariani
Phys. Rev. Lett. 69, 2935 – Published 16 November 1992
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Abstract

A side chain mesomorphic co-oligomer possesses a large blue-phase temperature domain. Upon cooling down from blue phase I colored crystallites are quenched below the glass transition of this material. The microtome cut of these crystallities and their observation by transmission electron microsocopy reveal the presence of biperiodic textures different from the cholesteric ones. Image analysis of these textures, associated with an original model of diffraction confirms the presence of the O8 symmetry and suggests that the transmission electron microscopy contrast obtained here has to be associated with changes of the molecular orientations in the bulk of the sample.

  • Received 1 May 1992

DOI:https://doi.org/10.1103/PhysRevLett.69.2935

©1992 American Physical Society

Authors & Affiliations

Hervé Delacroix, Jean-Marc Gilli, Inge Erk, and Paolo Mariani

  • Centre de Génétique Moléculaire, Centre National de la Recherche Scientifique, 91198 Gif-sur- Yvette CEDEX, France,
  • Faculté des Sciences de Nice, Para Valrose, 06034 Nice CEDEX, France
  • Istituto di Scienze Fisiche, Facoltà di Medicina, via Ranieri, I-60131, Ancona, Italy

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Issue

Vol. 69, Iss. 20 — 16 November 1992

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