Strain Pattern in Supercooled Liquids

Bernd Illing, Sebastian Fritschi, David Hajnal, Christian Klix, Peter Keim, and Matthias Fuchs
Phys. Rev. Lett. 117, 208002 – Published 8 November 2016
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Abstract

Investigations of strain correlations at the glass transition reveal unexpected phenomena. The shear strain fluctuations show an Eshelby-strain pattern [cos(4θ)/r2], characteristic of elastic response, even in liquids, at long times. We address this using a mode-coupling theory for the strain fluctuations in supercooled liquids and data from both video microscopy of a two-dimensional colloidal glass former and simulations of Brownian hard disks. We show that the long-ranged and long-lived strain signatures follow a scaling law valid close to the glass transition. For large enough viscosities, the Eshelby-strain pattern is visible even on time scales longer than the structural relaxation time τ and after the shear modulus has relaxed to zero.

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  • Received 14 June 2016

DOI:https://doi.org/10.1103/PhysRevLett.117.208002

© 2016 American Physical Society

Physics Subject Headings (PhySH)

Statistical Physics & ThermodynamicsCondensed Matter, Materials & Applied PhysicsPolymers & Soft Matter

Authors & Affiliations

Bernd Illing1, Sebastian Fritschi1, David Hajnal2,*, Christian Klix1, Peter Keim1, and Matthias Fuchs1

  • 1University of Konstanz, D-78457 Konstanz, Germany
  • 2Johannes Gutenberg-University Mainz, D-55099 Mainz, Germany

  • *Present Address: BASF SE, Carl-Bosch-Strasse 38, D-67056 Ludwigshafen, Germany.

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Issue

Vol. 117, Iss. 20 — 11 November 2016

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