Abstract
We study the effect of surfactant on the pairwise interactions of drops in an applied uniform dc electric field using a combination of numerical simulations based on a boundary integral formulation and an analytical theory assuming small drop deformations. The surfactant is assumed to be insoluble in the bulk-phase fluids. We show that the surfactant weakens the electrohydrodynamic flow, and thus dielectrophoretic interactions play a more prominent role in the dynamics of surfactant-covered drops compared to clean drops. If drop conductivity is the same as the suspending fluid, a nondiffusing surfactant can arrest the drops' relative motion thereby effectively preventing coalescence.
1 More- Received 2 December 2020
- Accepted 20 April 2021
DOI:https://doi.org/10.1103/PhysRevFluids.6.053601
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