When two oppositely charged drops come into light contact, a liquid meniscus bridge with double-cone geometry forms between the drops. Recent experiments have demonstrated the existence of a critical cone angle above which the meniscus bridge pinches off and the drops do not coalesce. This striking behavior—which has implications for processes ranging from the coarsening of emulsions to electrospray ionization in mass spectrometry—has been studied theoretically and experimentally for inertial liquid drops. Little is known, however, about the influence of the liquid viscosity on the critical cone angle. Here, we use high-fidelity numerical simulations to gain insight into the coalescence dynamics of conical drops at intermediate Reynolds numbers. The simulations, which account for viscous, inertial, and surface tension effects, predict that the critical cone angle increases as the viscosity of the drops decreases. When approaching the inertial regime, however, the predicted critical angle quickly stabilizes at approximately ${27}^{\circ }$, as observed in experiments.

• Received 26 October 2015

DOI:https://doi.org/10.1103/PhysRevE.93.023111