Solidification of a disk-shaped crystal from a weakly supercooled binary melt

David W. Rees Jones and Andrew J. Wells
Phys. Rev. E 92, 022406 – Published 24 August 2015

Abstract

The physics of ice crystal growth from the liquid phase, especially in the presence of salt, has received much less attention than the growth of snow crystals from the vapor phase. The growth of so-called frazil ice by solidification of a supercooled aqueous salt solution is consistent with crystal growth in the basal plane being limited by the diffusive removal of the latent heat of solidification from the solid-liquid interface, while being limited by attachment kinetics in the perpendicular direction. This leads to the formation of approximately disk-shaped crystals with a low aspect ratio of thickness compared to radius, because radial growth is much faster than axial growth. We calculate numerically how fast disk-shaped crystals grow in both pure and binary melts, accounting for the comparatively slow axial growth, the effect of dissolved solute in the fluid phase, and the difference in thermal properties between solid and fluid phases. We identify the main physical mechanisms that control crystal growth and show that the diffusive removal of both the latent heat released and the salt rejected at the growing interface are significant. Our calculations demonstrate that certain previous parametrizations, based on scaling arguments, substantially underestimate crystal growth rates by a factor of order 10–100 for low aspect ratio disks, and we provide a parametrization for use in models of ice crystal growth in environmental settings.

  • Figure
  • Figure
  • Figure
  • Figure
  • Figure
  • Figure
  • Figure
2 More
  • Received 10 April 2015

DOI:https://doi.org/10.1103/PhysRevE.92.022406

©2015 American Physical Society

Physics Subject Headings (PhySH)

  1. Research Areas
  1. Physical Systems
Statistical Physics & Thermodynamics

Authors & Affiliations

David W. Rees Jones* and Andrew J. Wells

  • Atmospheric, Oceanic and Planetary Physics, Department of Physics, University of Oxford, Clarendon Laboratory, Parks Road, Oxford OX1 3PU, UK

  • *David.ReesJones@physics.ox.ac.uk

Article Text (Subscription Required)

Click to Expand

References (Subscription Required)

Click to Expand
Issue

Vol. 92, Iss. 2 — August 2015

Reuse & Permissions
Access Options
Author publication services for translation and copyediting assistance advertisement

Authorization Required


×
×

Images

×

Sign up to receive regular email alerts from Physical Review E

Log In

Cancel
×

Search


Article Lookup

Paste a citation or DOI

Enter a citation
×