Diffusive mixing and Tsallis entropy

Daniel O'Malley, Velimir V. Vesselinov, and John H. Cushman
Phys. Rev. E 91, 042143 – Published 29 April 2015

Abstract

Brownian motion, the classical diffusive process, maximizes the Boltzmann-Gibbs entropy. The Tsallis q entropy, which is nonadditive, was developed as an alternative to the classical entropy for systems which are nonergodic. A generalization of Brownian motion is provided that maximizes the Tsallis entropy rather than the Boltzmann-Gibbs entropy. This process is driven by a Brownian measure with a random diffusion coefficient. The distribution of this coefficient is derived as a function of q for 1<q<3. Applications to transport in porous media are considered.

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  • Received 15 October 2014

DOI:https://doi.org/10.1103/PhysRevE.91.042143

©2015 American Physical Society

Authors & Affiliations

Daniel O'Malley and Velimir V. Vesselinov

  • Computational Earth Science, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA

John H. Cushman

  • Department of Earth, Atmospheric, and Planetary Sciences, Purdue University, West Lafayette, Indiana 47907, USA and Department of Mathematics, Purdue University, West Lafayette, Indiana 47907, USA

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Issue

Vol. 91, Iss. 4 — April 2015

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