Instantaneous gelation in Smoluchowski’s coagulation equation revisited

Robin C. Ball, Colm Connaughton, Thorwald H. M. Stein, and Oleg Zaboronski
Phys. Rev. E 84, 011111 – Published 11 July 2011

Abstract

We study the solutions of the Smoluchowski coagulation equation with a regularization term which removes clusters from the system when their mass exceeds a specified cutoff size, M. We focus primarily on collision kernels which would exhibit an instantaneous gelation transition in the absence of any regularization. Numerical simulations demonstrate that for such kernels with monodisperse initial data, the regularized gelation time decreases as M increases, consistent with the expectation that the gelation time is zero in the unregularized system. This decrease appears to be a logarithmically slow function of M, indicating that instantaneously gelling kernels may still be justifiable as physical models despite the fact that they are highly singular in the absence of a cutoff. We also study the case when a source of monomers is introduced in the regularized system. In this case a stationary state is reached. We present a complete analytic description of this regularized stationary state for the model kernel, K(m1,m2)=max{m1,m2}ν, which gels instantaneously when M if ν>1. The stationary cluster size distribution decays as a stretched exponential for small cluster sizes and crosses over to a power law decay with exponent ν for large cluster sizes. The total particle density in the stationary state slowly vanishes as [(ν1)logM]1/2 when M. The approach to the stationary state is nontrivial: Oscillations about the stationary state emerge from the interplay between the monomer injection and the cutoff, M, which decay very slowly when M is large. A quantitative analysis of these oscillations is provided for the addition model which describes the situation in which clusters can only grow by absorbing monomers.

  • Figure
  • Figure
  • Figure
  • Figure
  • Figure
  • Figure
  • Figure
  • Received 21 December 2010

DOI:https://doi.org/10.1103/PhysRevE.84.011111

©2011 American Physical Society

Authors & Affiliations

Robin C. Ball1,2,*, Colm Connaughton1,3,†, Thorwald H. M. Stein4,‡, and Oleg Zaboronski3,§

  • 1Centre for Complexity Science, University of Warwick, Gibbet Hill Road, Coventry CV4 7AL, United Kingdom
  • 2Department of Physics, University of Warwick, Gibbet Hill Road, Coventry CV4 7AL, United Kingdom
  • 3Mathematics Institute, University of Warwick, Gibbet Hill Road, Coventry CV4 7AL, United Kingdom
  • 4Department of Meteorology, University of Reading, Earley Gate, Reading RG6 6BB, United Kingdom

  • *R.C.Ball@warwick.ac.uk
  • connaughtonc@gmail.com
  • t.h.stein@reading.ac.uk
  • §O.V.Zaboronski@warwick.ac.uk

Article Text (Subscription Required)

Click to Expand

References (Subscription Required)

Click to Expand
Issue

Vol. 84, Iss. 1 — July 2011

Reuse & Permissions
Access Options
Author publication services for translation and copyediting assistance advertisement

Authorization Required


×
×

Images

×

Sign up to receive regular email alerts from Physical Review E

Log In

Cancel
×

Search


Article Lookup

Paste a citation or DOI

Enter a citation
×