Central role of thermal collective strain in the relaxation of structure in a supercooled liquid

Asaph Widmer-Cooper and Peter Harrowell
Phys. Rev. E 80, 061501 – Published 16 December 2009

Abstract

The spatial distribution of structural relaxation in a supercooled liquid is studied using molecular dynamics simulations of a two-dimensional binary mixture. It is shown that the spatial heterogeneity of the relaxation along with the time scale of the relaxation is determined, not by the frequency with which particles move a distance π/2kBragg, but by the frequency with which particles can achieve persistent displacements. We show that these persistent displacements are achieved through the coupled action of local reorganizations and unrecoverable thermal strains.

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  • Received 7 June 2009

DOI:https://doi.org/10.1103/PhysRevE.80.061501

©2009 American Physical Society

Authors & Affiliations

Asaph Widmer-Cooper1,2 and Peter Harrowell1

  • 1School of Chemistry, University of Sydney, Sydney, New South Wales 2006, Australia
  • 2Materials Science Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA

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Vol. 80, Iss. 6 — December 2009

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