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Dielectric spectroscopy in benzophenone: The β relaxation and its relation to the mode-coupling Cole-Cole peak

L. C. Pardo, P. Lunkenheimer, and A. Loidl
Phys. Rev. E 76, 030502(R) – Published 28 September 2007

Abstract

We report a thorough characterization of the glassy dynamics of benzophenone by broadband dielectric spectroscopy. We detect a well-pronounced β relaxation peak developing into an excess wing with increasing temperature. A previous analysis of results from Optical-Kerr-effect measurements of this material within the mode-coupling theory revealed a high-frequency Cole-Cole peak. We address the question if this phenomenon also may explain the Johari-Goldstein β relaxation, a so-far unexplained spectral feature inherent to glass-forming matter, mainly observed in dielectric spectra. Our results demonstrate that according to the present status of theory, both spectral features seem not to be directly related.

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  • Received 18 July 2007

DOI:https://doi.org/10.1103/PhysRevE.76.030502

©2007 American Physical Society

Authors & Affiliations

L. C. Pardo1,2, P. Lunkenheimer1,*, and A. Loidl1

  • 1Experimental Physics V, Center for Electronic Correlations and Magnetism, University of Augsburg, 86135 Augsburg, Germany
  • 2Departament de Física i Enginyeria Nuclear, ETSEIB, Universitat Politècnica de Catalunya, Diagonal 647, 08028 Barcelona, Catalonia, Spain

  • *Corresponding author. peterl@Physik.Uni-Augsburg.de

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Issue

Vol. 76, Iss. 3 — September 2007

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