Rheology of defect networks in cholesteric liquid crystals

Laurence Ramos, Martin Zapotocky, T. C. Lubensky, and D. A. Weitz
Phys. Rev. E 66, 031711 – Published 25 September 2002
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Abstract

The rheological properties of cholesteric liquid crystals containing networks of defects are investigated. A network of linear defects of the “oily-streak” type is stabilized when colloidal particles are dispersed into the cholesteric liquid crystals. This network converts the rheological response of a presheared cholesteric liquid crystal from fluidlike to solidlike and leads to the formation of a “defect-mediated” solid. The frequency-dependent complex shear modulus G*(ω) is measured, for samples with and without inclusions, in both the linear and nonlinear viscoelastic regimes. The linear elastic response mediated by the defect network is discussed in terms of a model analogous to the theories of rubber elasticity. All our data for G*(ω) are fitted to a simplified theoretical form, and the values and variations of the fitting parameters, in the various regimes investigated, are discussed in terms of the properties of defect structure present in the samples. Similar rheological properties are expected to arise from particle-stabilized oily-streak defect networks in layered systems such as smectic-A and lyotropic Lα phases.

  • Received 3 August 2001

DOI:https://doi.org/10.1103/PhysRevE.66.031711

©2002 American Physical Society

Authors & Affiliations

Laurence Ramos*, Martin Zapotocky, T. C. Lubensky, and D. A. Weitz

  • Department of Physics and Astronomy, University of Pennsylvania, Philadelphia, Pennsylvania 19104

  • *Present address: Groupe de Dynamique des Phases Condensées (UMR CNRS-UM2 5581), CC26, Université Montpellier 2, 34095 Montpellier Cedex 5, France.
  • Present address: Center for Studies in Physics and Biology, The Rockefeller University, 1230 York Avenue, New York, NY 10021.
  • Present address: Department of Physics and DEAS, Harvard University, Cambridge, MA 02138.

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Vol. 66, Iss. 3 — September 2002

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