Critical behavior of gelation probed by the dynamics of latex spheres

G. C. Fadda, D. Lairez, and J. Pelta
Phys. Rev. E 63, 061405 – Published 23 May 2001
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Abstract

We report a quasielastic light scattering study of the dynamics of large latex probe particles (R=225nm) in gelatin solution undergoing gelation. We show that by focusing on the short-time and long-time behavior of the autocorrelation function, it is possible to simply interpret out data in terms of the divergence of the viscosity and emergence of the shear elastic modulus near the gel point. Our crude analysis allows us to grasp the critical behavior of gelation and to obtain the two critical exponents of the transport properties.

  • Received 21 November 2000

DOI:https://doi.org/10.1103/PhysRevE.63.061405

©2001 American Physical Society

Authors & Affiliations

G. C. Fadda and D. Lairez*

  • Laboratoire Léon Brillouin, CEA-CNRS, CEA/Saclay, 91191 Gif-sur-Yvette cedex, France

J. Pelta

  • ERRMECE, Université de Cergy-Pontoise, 95302 Cergy-Pontoise cedex, France

  • *Author to whom correspondence should be addressed.

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Issue

Vol. 63, Iss. 6 — June 2001

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