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Doubly anchored nematic polymer brushes: Shear, field effects, and quasipiezoelectricity

A. Halperin and D. R. M. Williams
Phys. Rev. E 49, R986(R) – Published 1 February 1994
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Abstract

The shear behavior of a doubly anchored brush of liquid-crystalline polymers immersed in a nematic solvent is investigated. In such a brush the grafted polymers bridge two plates. Remarkably, the Franck nematic elasticity in this system can dominate the shear modulus. In the presence of a field the system undergoes a Fréedericksz transition modified by the bridging polymers. In particular: (i) the polymeric elasticity affects the critical field Ec; (ii) the shear modulus vanishes as the field approaches Ec; and (iii) the nematic distortion couples to a shear strain. The system exhibits quasipiezoelectricity, which is nonlinear and is not associated with any inverse effect.

  • Received 27 August 1993

DOI:https://doi.org/10.1103/PhysRevE.49.R986

©1994 American Physical Society

Authors & Affiliations

A. Halperin and D. R. M. Williams

  • Laboratoire Léon Brillouin, Centre d’Etudes Nucléaires de Saclay, 91191 Gif-sur-Yvette Cedex, France
  • Laboratoire de Physique de la Matière Condensée, Collège de France, 75231 Paris Cedex 05, France

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Vol. 49, Iss. 2 — February 1994

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