Influence of facets on solid state dewetting mechanisms: Comparison between Ge and Si on SiO2

F. Leroy, F. Cheynis, T. Passanante, and P. Müller
Phys. Rev. B 88, 035306 – Published 15 July 2013

Abstract

The dewetting properties of Ge/SiO2 have been studied by low-energy electron microscopy and grazing incidence small-angle x-ray scattering in two temperature ranges characterized by the presence or the absence of {15 3 23} facets on the dewetting fronts. Thanks to a comparison with the Si/SiO2 system, we show that the {15 3 23} facets: (i) play a role in the stabilization properties of Ge dewetting fronts, (ii) lead to a rotation of 45 of the Ge fingers with respect to the Si fingers, and (iii) increase the Ge fingers’ stability delaying the formation of a three-dimensional Ge islands with respect to Si for the benefit of the formation of Ge nanowires. Studying the dewetting kinetics enables estimating the activation energy for Ge dewetting to 2.7±0.2eV. The weak energetics differences between Si and Ge systems are sufficient to change the dewetting morphologies from a squared-void opening for Si/SiO2 to multibranch dendrites for Ge with specific consequences on the relative dewetting velocities of the Si/SiO2 and Ge/SiO2 systems.

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  • Received 7 May 2013

DOI:https://doi.org/10.1103/PhysRevB.88.035306

©2013 American Physical Society

Authors & Affiliations

F. Leroy*, F. Cheynis, T. Passanante, and P. Müller

  • CINaM, UMR CNRS 7325, Campus de Luminy, Aix-Marseille University, 13288 Marseille Cedex, France

  • *leroy@cinam.univ-mrs.fr
  • cheynis@cinam.univ-mrs.fr
  • muller@cinam.univ-mrs.fr

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Issue

Vol. 88, Iss. 3 — 15 July 2013

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