Local structure of binary mixtures has been usually determined by diffraction techniques. In the past few years the analysis of x-ray absorption spectroscopy data has been proved to be a powerful tool for an accurate determination of the structure of solid and liquid systems, complementary to x-ray or neutron scattering methods. In this paper we report about a procedure to extract pair correlation functions of liquid and disordered binary mixtures from x-ray absorption fine structure (XAFS) data, satisfying both long-distance behavior and long wavelength limit of Bhatia-Thornton structure factors. An application to accurate XAFS data collected on a $\mathrm{CuSn}$ binary metal alloy $\left(\mathrm{Cu}6\mathrm{Sn}5\right)$ is reported and compared with existing models.

• Received 12 November 2003

DOI:https://doi.org/10.1103/PhysRevB.70.014101