Abstract
We study the effects of weak off-diagonal disorder on Peierls systems with a doubly degenerate ground state. We show that for these systems disorder in the electron hopping amplitudes induces a finite density of solitons in the minimal-energy lattice configuration of a single chain. These disorder-induced dimerization kinks are neutral and have spin . Using a continuum model for the Peierls chain and treating the lattice classically, we analytically calculate the average free energy and density of kinks. We compare these results to numerical calculations for a discrete model and discuss the implications of the kinks for the optical and magnetic properties of the conjugated polymer trans-polyacetylene.
- Received 8 July 1997
DOI:https://doi.org/10.1103/PhysRevB.57.2861
©1998 American Physical Society