Incipient oxidation of magnesium: A high-resolution electron-energy-loss and photoemission study

P. A. Thiry, J. Ghijsen, R. Sporken, J. J. Pireaux, R. L. Johnson, and R. Caudano
Phys. Rev. B 39, 3620 – Published 15 February 1989
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Abstract

The initial stages of magnesium oxidation are investigated by high-resolution electron-energy-loss spectroscopy. Two species (magnesium oxide and chemisorbed oxygen) are simultaneously detected from their vibrational bands even for minimal oxygen exposures. The evolution of the surface oxide can be quantitatively described by dielectric theory using infrared optical constants deduced from measurements on MgO single crystals. The proposed oxidation model is confirmed by the Mg 2p electron-distribution curves obtained with synchrotron radiation.

  • Received 11 July 1988

DOI:https://doi.org/10.1103/PhysRevB.39.3620

©1989 American Physical Society

Authors & Affiliations

P. A. Thiry

  • Laboratoire Interdisciplinaire de Spectroscopie Electronique, Institut de Recherches sur les Interfaces Solides, Facultés Universitaires Notre-Dame de la Paix, 61 rue de Bruxelles, B-5000 Namur, Belgium

J. Ghijsen

  • Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, Postfach 80 06 65, D-7000 Stuttgart 80, Federal Republic of Germany

R. Sporken and J. J. Pireaux

  • Laboratoire Interdisciplinaire de Spectroscopie Electronique, Institut de Recherches sur les Interfaces Solides, Facultés Universitaires Notre-Dame de la Paix, 61 rue de Bruxelles, B-5000 Namur, Belgium

R. L. Johnson

  • Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, Postfach 80 06 65, D-7000 Stuttgart 80, Federal Republic of Germany

R. Caudano

  • Laboratoire Interdisciplinaire de Spectroscopie Electronique, Institut de Recherches sur les Interfaces Solides, Facultés Universitaires Notre-Dame de la Paix, 61 rue de Bruxelles, B-5000 Namur, Belgium

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Vol. 39, Iss. 6 — 15 February 1989

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