Abstract
A series of new -like materials are reported in which the oxygen content and the average [Cu-O] charge (or Cu valence) are separately varied over a wide range. We find a distinct boundary between samples showing anomalous insulating behavior and those with high . These data are interpreted to demonstrate that the [Cu-O] charge in the sheets largely determines and that the variable oxygen content and the chains merely provide an insulating reservoir of charge.
- Received 19 April 1988
DOI:https://doi.org/10.1103/PhysRevB.38.7156
©1988 American Physical Society