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Analog metal-to-nonmetal exciton transition: Effect of isotopic alloying on naphthalene triplet transport

Stuart T. Gentry and Raoul Kopelman
Phys. Rev. B 27, 2579(R) – Published 15 February 1983
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Abstract

A low-temperature investigation of the rate of triplet exciton transport within the guest (C10H8) quasilattice of the C10D8-C10H8 crystal system has demonstrated a transition from bandlike to hoppinglike motion upon reduction of the guest-to-host concentration ratio. The analog metal and nonmetal regimes are characterized, respectively, by a negative and a positive transport temperature coefficient. In addition, reducing the naphthalene concentration by a factor of 5 reduces the transport rate by five orders of magnitude.

  • Received 13 September 1982

DOI:https://doi.org/10.1103/PhysRevB.27.2579

©1983 American Physical Society

Authors & Affiliations

Stuart T. Gentry and Raoul Kopelman

  • Department of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109

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Issue

Vol. 27, Iss. 4 — 15 February 1983

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