Abstract
Near-edge x-ray-absorption fine-structure spectra are reported above the absorption edges of diatomic low- molecules (CO, NO, and ) chemisorbed on Ni(100). It is shown that the -edge fine structure is dominated by intramolecular resonances which arise from a sharp bound-state transition to an unoccupied molecular orbital of symmetry and a broader shape resonance in the continuum. For dissociated molecules the absorption-edge structure is found to be distinctly different, and large (∼3 eV) shifts of the edge position are observed. The position of the molecular resonances is discussed in comparison with gas-phase absorption data and the binding energies determined by photoemission. The question of ligand and metal charge transfer is discussed for the neutral and ionic (core-hole) chemisorption complex. For on Ni(100) the giant satellite structure in the N photoemission spectrum due to dynamic screening of the core hole has been measured at eV, and comparison is made with the absorption case. A theoretical expression is derived for the polarization dependence of the resonance structures which allows the precise determination of the molecular orientation on the surface. Comparison is made to the theory governing angle-resolved photoemission spectra. The molecular orientation for CO, NO, and on Ni(100) at saturation coverage is determined. All molecules are found to stand up on the surface with the molecular axis along the surface normal (±10°).
- Received 10 May 1982
DOI:https://doi.org/10.1103/PhysRevB.26.4111
©1982 American Physical Society