Kauzmann paradox: A possible crossover due to diminishing local excitations

Xin-Yuan Gao, Chin-Yuan Ong, Chun-Shing Lee, Cho-Tung Yip, Hai-Yao Deng, and Chi-Hang Lam
Phys. Rev. B 107, 174206 – Published 12 May 2023

Abstract

The configurational entropy of supercooled liquids extrapolates to zero at the Kauzmann temperature, causing a crisis called the Kauzmann paradox. Here, using a class of multicomponent lattice glass models, we study a resolution of the paradox characterized by a sudden but smooth turn in the entropy as temperature goes sufficiently low. A scalar variant of the models reproduces the Kauzmann paradox with thermodynamic properties at very low temperatures dominated by correlations. An exactly solvable vector variant without correlation illustrates that a sudden entropy turn occurs when discrete local excitations are largely suppressed. Despite being disordered and infinitely degenerate, the ground states have zero entropy per particle.

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  • Received 2 September 2022
  • Revised 13 February 2023
  • Accepted 24 April 2023

DOI:https://doi.org/10.1103/PhysRevB.107.174206

©2023 American Physical Society

Physics Subject Headings (PhySH)

  1. Physical Systems
Statistical Physics & Thermodynamics

Authors & Affiliations

Xin-Yuan Gao1,2, Chin-Yuan Ong2, Chun-Shing Lee2, Cho-Tung Yip3,*, Hai-Yao Deng4,†, and Chi-Hang Lam2,‡

  • 1Department of Physics, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, China
  • 2Department of Applied Physics, Hong Kong Polytechnic University, Hong Kong, China
  • 3Department of Physics, Harbin Institute of Technology, Shenzhen 518055, China
  • 4School of Physics and Astronomy, Cardiff University, 5 The Parade, Cardiff CF24 3AA, Wales, United Kingdom

  • *h0260416@hit.edu.cn
  • dengh4@cardiff.ac.uk
  • C.H.Lam@polyu.edu.hk

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Issue

Vol. 107, Iss. 17 — 1 May 2023

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