High-order perturbation theory of the imaginary part of the resonance eigenvalues of the Stark effect in hydrogen and of the anharmonic oscillator with negative anharmonicity

Harris J. Silverstone, Evans Harrell, and Christina Grot
Phys. Rev. A 24, 1925 – Published 1 October 1981
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Abstract

The "perturbation theory" for the imaginary part of the resonance energies of the hydrogen atom in the Stark effect and of the two-dimensional anharmonic oscillator with negative anharmonicity, which is a separation constant in the Stark problem, is solved to high order. The solution is based on the Langer-Cherry generalization of the JWKB method, which can be carried out in closed form, order by order. The numerical results should be useful both in interpreting experimental measurements of excited-state lifetimes and in understanding the analytic properties of the Stark and anharmonic-oscillator resonances.

  • Received 29 December 1980

DOI:https://doi.org/10.1103/PhysRevA.24.1925

©1981 American Physical Society

Authors & Affiliations

Harris J. Silverstone

  • Department of Chemistry, The Johns Hopkins University, Baltimore, Maryland 21218

Evans Harrell and Christina Grot

  • Department of Mathematics, The Johns Hopkins University, Baltimore, Maryland 21218

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Vol. 24, Iss. 4 — October 1981

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