Microstructure and Dynamics near an Attractive Colloidal Glass Transition

D. Pontoni, T. Narayanan, J.-M. Petit, G. Grübel, and D. Beysens
Phys. Rev. Lett. 90, 188301 – Published 5 May 2003

Abstract

The microstructure and dynamics of a colloidal system interacting via short-ranged interparticle potential is studied by ultra-small-angle x-ray scattering and x-ray photon correlation spectroscopy. A colloidal gas-liquid type transition is induced when the short-ranged attractive interactions attain sufficient magnitude. The development of liquidlike structure is preceded by a systematic transition in the particle dynamics from diffusive to constrained motion and then completely frozen behavior. This demonstrates the existence of a jamming transition induced by strong short-ranged attractive interactions even at low packing fractions.

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  • Received 6 February 2003

DOI:https://doi.org/10.1103/PhysRevLett.90.188301

©2003 American Physical Society

Authors & Affiliations

D. Pontoni1, T. Narayanan1,*, J.-M. Petit1,†, G. Grübel1, and D. Beysens2

  • 1European Synchrotron Radiation Facility, 38043 Grenoble, France
  • 2CEA-ESEME, ICMCB, 87, Avenue Dr. A. Schweitzer, 33608 Pessac, France

  • *Corresponding author. Email address: narayan@esrf.fr
  • Present address: L’Oreal Research, F-92583, Clichy cedex, France.

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Issue

Vol. 90, Iss. 18 — 9 May 2003

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