Excitons confined to CdSe/ZnSe self-assembled quantum dots are probed through a nanoaperture using time-resolved photoluminescence. Significant evidence is shown that two different electronic states are associated with these dots, with binding energies which differ by an order of magnitude. The first has a short 450 ps lifetime, exhibits a relatively broad emission line, and persists nearly to room temperature; the second exhibits a long $(>4\mathrm{}\mathrm{ns})$ lifetime and is responsible for the sharp $\left(\sim 100\mu \mathrm{eV}\right)$ lines seen at low temperatures $(<60\mathrm{}\mathrm{K})$. These results are completely unlike those seen in III-V dots, and reveal the complexity of the electronic structure in CdSe dots.

• Received 27 April 1999

DOI:https://doi.org/10.1103/PhysRevLett.83.2797