Abstract
Structural properties of carbon peapods, , trapped into single-walled carbon nanotubes (SWNT), have been studied under high-pressure/high-temperature conditions (HPHT) by in situ x-ray diffraction. The chain structure together with the influence of the filling on the SWNT change under HPHT treatment is investigated. Synthesis of a one-dimensional polymer chain of inside the single-walled carbon nanotubes is evidenced. At , increasing the temperature up to leads to a progressive polymerization that is associated to a shortening of distance down to . Back to ambient conditions, the chain remains polymerized, emphasizing the high stability of this material. In addition, our data strongly suggest a symmetry change of the two-dimensional bunde lattice under pressure.
- Received 11 September 2006
DOI:https://doi.org/10.1103/PhysRevB.74.205425
©2006 American Physical Society