Abstract
and NMR measurements are reported for , HD, and dissolved in various nematic phases. The main results are the following: Signs of order parameters are liquid-crystal dependent; the molecules with larger average bond lengths show smaller order parameters; the order parameters for ortho- and para-deuterium are equal within experimental error; the ratios of quadrupolar to dipolar couplings in HD and are about seven percent lower than in the gas phase. These results are rationalized in terms of environmental effects of the liquid-crystal field on the dissolved molecules. This field decreases the quadrupolar coupling in HD and and causes extensive mixing of different rotational states of the hydrogens in the liquid phase. The observed isotope dependence of the average orientation is a quantum-mechanical effect which can be explained by the influence of a simple one-parameter mean liquid-crystal field on the rotational energies and rotational wave functions of the hydrogens.
- Received 28 September 1981
DOI:https://doi.org/10.1103/PhysRevA.25.2339
©1982 American Physical Society