Validity of the Franck-Condon Principle in the Optical Spectroscopy: Optical Conductivity of the Fröhlich Polaron

G. De Filippis, V. Cataudella, A. S. Mishchenko, C. A. Perroni, and J. T. Devreese
Phys. Rev. Lett. 96, 136405 – Published 6 April 2006

Abstract

The optical absorption of the Fröhlich polaron model is obtained by an approximation-free diagrammatic Monte Carlo method and compared with two new approximate approaches that treat lattice relaxation effects in different ways. We show that: (i) a strong coupling expansion, based on the Franck-Condon principle, well describes the optical conductivity for large coupling strengths (α>10); (ii) a memory function formalism with phonon broadened levels reproduces the optical response for weak coupling strengths (α<6) taking the dynamic lattice relaxation into account. In the coupling regime 6<α<10, the optical conductivity is a rapidly changing superposition of both Franck-Condon and dynamic contributions.

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  • Received 30 January 2006

DOI:https://doi.org/10.1103/PhysRevLett.96.136405

©2006 American Physical Society

Authors & Affiliations

G. De Filippis1, V. Cataudella1, A. S. Mishchenko2,3, C. A. Perroni4, and J. T. Devreese5

  • 1Coherentia CNR-INFM and Dipartimento di Scienze Fisiche, Università di Napoli Federico II, I-80126 Napoli, Italy
  • 2CREST, Japan Science and Technology Agency (JST), AIST, 1-1-1 Higashi, Tsukuba 305-8562, Japan
  • 3RRC “Kurchatov Institute,” 123182 Moscow, Russia
  • 4Institute of Solid State Research (IFF), Research Center Jülich, Jülich, D-52425, Germany
  • 5TFVS, Departement Fysica, Universiteit Antwerpen, Universiteitsplein 1, B2610 Antwerpen, Belgium

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Vol. 96, Iss. 13 — 7 April 2006

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