Dynamic Self-Assembly of Rings of Charged Metallic Spheres

Bartosz A. Grzybowski, Jason A. Wiles, and George M. Whitesides
Phys. Rev. Lett. 90, 083903 – Published 26 February 2003
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Abstract

This Letter describes dynamic self-assembly in a system of stainless steel spheres (1mm in diameter) rolling on a flat dielectric surface under the influence of an external magnetic field that rotates parallel to the plane of the surface. As the spheres move, they charge triboelectrically. Self-assembly is mediated by two types of electrostatic interactions among these charges: (i) attraction between negatively charged regions of the surface and positively charged spheres and (ii) repulsion between the like-charged spheres. The spheres organize into highly ordered rings as a result of these electrostatic interactions.

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  • Received 15 November 2001

DOI:https://doi.org/10.1103/PhysRevLett.90.083903

©2003 American Physical Society

Authors & Affiliations

Bartosz A. Grzybowski*, Jason A. Wiles, and George M. Whitesides*

  • Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138

  • *To whom correspondence should be addressed.

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Issue

Vol. 90, Iss. 8 — 28 February 2003

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