Fast Relaxation in a Fragile Liquid under Pressure

A. Tölle, H. Schober, J. Wuttke, O. G. Randl, and F. Fujara
Phys. Rev. Lett. 80, 2374 – Published 16 March 1998
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Abstract

The incoherent dynamic structure factor of orthoterphenyl is studied by quasielastic neutron scattering to 240 MPa. Tagged-particle correlations in the compressed liquid decay in two steps. The α-relaxation line shape is independent of pressure, and the relaxation time proportional to viscosity. A kink in the amplitude fQ(P) reveals the onset of β relaxation. The β-relaxation regime can be described by the mode-coupling scaling function; amplitudes and time scales allow a consistent determination of the critical pressure Pc(T). α and β relaxation depend in the same way on the thermodynamic state; close to Pc(T), this dependence can be parametrized by an effective coupling ΓnT1/4.

  • Received 5 June 1997

DOI:https://doi.org/10.1103/PhysRevLett.80.2374

©1998 American Physical Society

Authors & Affiliations

A. Tölle1,2, H. Schober1, J. Wuttke3, O. G. Randl1,*, and F. Fujara2

  • 1Institut Laue-Langevin, 38042 Grenoble, France
  • 2Fachbereich Physik, Universität Dortmund, 44221 Dortmund, Germany
  • 3Physik-Department, Technische Universität München, 85747 Garching, Germany

  • *Present address: Michelin, place des Carmes, 63040 Clermont-Ferrand Cedex.

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Vol. 80, Iss. 11 — 16 March 1998

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