Universality in the Critical Broadening of Spectral Lines in Simple Fluids

Shaul Mukamel, Peter S. Stern, and David Ronis
Phys. Rev. Lett. 50, 590 – Published 21 February 1983
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Abstract

Nonlinear mode-coupling hydrodynamics is used to study the broadening of spectral lines near a liquid-gas critical point. The critical contribution to the line shape is given by a universal line-shape function. For values of ε=|(TTc)Tc| which are not too small, the line assumes a Lorentzian form and the width Γ^ increases as εs with the critical exponent s=γ+ν=0.607. Very close to the critical point the line changes into a Levy distribution [the Fourier transform of exp(tr) where r=(3η)2] and the line shape becomes independent of ε (s=0).

  • Received 7 September 1982

DOI:https://doi.org/10.1103/PhysRevLett.50.590

©1983 American Physical Society

Authors & Affiliations

Shaul Mukamel

  • Department of Chemistry, University of Rochester, Rochester, New York 14627

Peter S. Stern

  • Chemical Physics Department, Weizmann Institute of Science, Rehovot, Israel 76100

David Ronis

  • Department of Chemistry, Harvard University, Cambridge, Massachusetts 02138

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Vol. 50, Iss. 8 — 21 February 1983

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