Theory of Structural Variation in a Quasi-One-Dimensional Conductor

L. J. Sham and Bruce R. Patton
Phys. Rev. Lett. 36, 733 – Published 29 March 1976
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Abstract

Neutron-scattering studies of the quasi-one-dimensional conductor K2Pt(CN)4Br0.30·H2O demonstrate not only the existence of soft phonon modes but also the coexistence of central peaks and the development of a superlattice on cooling which, however, never becomes a true structural phase transition. We suggest that the central peak is due to bromine-induced, static, platinum-chain distortion and show that it affects the electronic motion sufficiently to create a strong enough fluctuation in the three-dimensional system to remove the expected phase transition.

  • Received 12 March 1975

DOI:https://doi.org/10.1103/PhysRevLett.36.733

©1976 American Physical Society

Authors & Affiliations

L. J. Sham*

  • IBM Thomas J. Watson Research Center, Yorktown Heights, New York 10598

Bruce R. Patton

  • Department of Physics, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139

  • *On leave of absence from University of California at San Diego, San Diego, Calif. 92037.
  • Summer visitor at IBM. Work partially supported by the National Science Foundation. Alfred P. Sloan Fellow.

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Vol. 36, Iss. 13 — 29 March 1976

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