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Electro-optic technique to study biaxiality of liquid crystals with positive dielectric anisotropy: The case of a bent-core material

Khoa Van Le, Manoj Mathews, Martin Chambers, John Harden, Quan Li, Hideo Takezoe, and Antal Jákli
Phys. Rev. E 79, 030701(R) – Published 26 March 2009

Abstract

We propose that, for materials having positive dielectric anisotropy, the biaxiality can be clearly verified or excluded by measuring the transmitted light intensity as a function of electric field. If the material is biaxial and is observed in homeotropically aligned cells, the schlieren texture should not disappear (transmitted intensity is not zero) even at very high fields, since the field does not affect the distribution of the second director normal to the main director. On the other hand, if the material is uniaxial the transmitted intensity should decrease with increasing field and a perfect homeotropic texture can be achieved at high fields. We have studied a bent-core compound in which a uniaxial-biaxial nematic (NuNb) transition has been reported. This material has a positive dielectric anisotropy at low frequencies, so we could apply the technique described above. Our studies indicate that the material is uniaxial in the entire nematic range.

    • Received 5 November 2008

    DOI:https://doi.org/10.1103/PhysRevE.79.030701

    ©2009 American Physical Society

    Authors & Affiliations

    Khoa Van Le1, Manoj Mathews2, Martin Chambers2,3, John Harden2, Quan Li2, Hideo Takezoe1,*, and Antal Jákli2

    • 1Department of Organic and Polymeric Materials, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8552, Japan
    • 2Liquid Crystal Institute and Chemical Physics Interdisciplinary Program, Kent State University, Kent, Ohio 44242, USA
    • 3Department of Physics, Kent State University, Kent, Ohio 44242, USA

    • *Corresponding author. takezoe.h.aa@m.titech.ac.jp

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    Issue

    Vol. 79, Iss. 3 — March 2009

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