Dipole fluid as a basic model for the equation of state of ionic liquids in the vicinity of their critical point

V. L. Kulinskii and N. P. Malomuzh
Phys. Rev. E 67, 011501 – Published 7 January 2003
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Abstract

A model of dipole fluid for ionic liquids similar to molten NaCl is proposed. The estimates for the critical parameters are obtained with the help of the van der Waals equation of state. The influence of the rotation on the characteristics of a dipole pair and the location of the critical point is discussed. The dissociation of such a fluid near the critical point is considered.

  • Received 21 February 2002

DOI:https://doi.org/10.1103/PhysRevE.67.011501

©2003 American Physical Society

Authors & Affiliations

V. L. Kulinskii* and N. P. Malomuzh†

  • Department of Theoretical Physics, Odessa National University, 2 Dvoryanskaya, 270100 Odessa, Ukraine

  • *Electronic address: koul@paco.net
  • †Electronic address: mnp@ukr.net

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Vol. 67, Iss. 1 — January 2003

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