Reexamination of the depolarized-light-scattering spectra of glass-forming liquids

Xiao Cheng Zeng, Daniel Kivelson, and Gilles Tarjus
Phys. Rev. E 50, 1711 – Published 1 August 1994
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Abstract

We reexamine the depolarized-light-scattering data of Cummins and co-workers [Phys. Rev. A 45, 3867 (1992); 46, 3343 (1992); Phys. Rev. E 47, 4223 (1993)] and interpret these data rather differently than they. These authors make use of the mode-coupling theory of glasses which makes a number of significant predictions that have been associated with the observed behavior of supercooled liquids as they approach the glassy state. To date the strongest experimental support for the mode-coupling theory of glasses comes from the analysis by Cummins and co-workers of their depolarized-light-scattering data. For this reason it is particularly important to subject this analysis to careful scrutiny. Our conclusion is that these data do not show strong evidence for the critical behavior predicted by the mode-coupling theory of glasses.

  • Received 4 June 1993

DOI:https://doi.org/10.1103/PhysRevE.50.1711

©1994 American Physical Society

Authors & Affiliations

Xiao Cheng Zeng and Daniel Kivelson

  • Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, California 90024

Gilles Tarjus

  • Laboratoire de Physique Théorique des Liquides, Université Pierre et Marie Curie, 4 Place Jussieu, 75252 Paris Cedex 05, France

Original Article

Light-scattering spectroscopy of the liquid-glass transition in CaKNO3 and in the molecular glass Salol: Extended-mode-coupling-theory analysis

H. Z. Cummins, W. M. Du, M. Fuchs, W. Götze, S. Hildebrand, A. Latz, G. Li, and N. J. Tao
Phys. Rev. E 47, 4223 (1993)

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Vol. 50, Iss. 2 — August 1994

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