Time-translational symmetry in statistical dynamics dictates Einstein relation, Green-Kubo formula, and their generalizations

Ying-Jen Yang and Hong Qian
Phys. Rev. E 107, 024110 – Published 9 February 2023

Abstract

A stochastic dynamics has a natural decomposition into a drift capturing mean rate of change and a martingale increment capturing randomness. They are two statistically uncorrelated, but not necessarily independent, components contributing to the overall fluctuations of the dynamics, representing the uncertainties in the past and in the future. We show that fluctuation-dissipation relations of the two aforementioned components, such as the Einstein relation and the Green-Kubo formula, can be formulated for any stochastic process with a steady state, without additional supposition of the process being Markovian, reversible, or linear. Further, by considering the adjoint process defined by the time reversal at the steady state, we show that reversibility in equilibrium leads to an additional symmetry in the covariance between system's state and drift. Potential directions of further generalizing our results to processes without steady states is briefly discussed.

  • Figure
  • Received 2 June 2022
  • Accepted 23 January 2023

DOI:https://doi.org/10.1103/PhysRevE.107.024110

©2023 American Physical Society

Physics Subject Headings (PhySH)

Statistical Physics & Thermodynamics

Authors & Affiliations

Ying-Jen Yang*

  • Laufer Center for Physical and Quantitative Biology, State University of New York, Stony Brook, New York 11794, USA

Hong Qian

  • Department of Applied Mathematics, University of Washington, Seattle, Washington 98195, USA

  • *ying-jen.yang@stonybrook.edu
  • hqian@uw.edu

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Vol. 107, Iss. 2 — February 2023

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