Deformations, relaxation, and broken symmetries in liquids, solids, and glasses: A unified topological field theory

Matteo Baggioli, Michael Landry, and Alessio Zaccone
Phys. Rev. E 105, 024602 – Published 9 February 2022

Abstract

We combine hydrodynamic and field theoretic methods to develop a general theory of phonons as Goldstone bosons in crystals, glasses, and liquids based on nonaffine displacements and the consequent Goldstone phase relaxation. We relate the conservation, or lack thereof, of specific higher-form currents with properties of the underlying deformation field—nonaffinity—which dictates how molecules move under an applied stress or deformation. In particular, the single-valuedness of the deformation field is associated with conservation of higher-form charges that count the number of topological defects. Our formalism predicts, from first principles, the presence of propagating shear waves above a critical wave vector in liquids, thus giving a formal derivation of the phenomenon in terms of fundamental symmetries. The same picture provides also a theoretical explanation of the corresponding “positive sound dispersion” phenomenon for longitudinal sound. Importantly, accordingly to our theory, the main collective relaxation timescale of a liquid or a glass (known as the α relaxation for the latter) is given by the phase relaxation time, which is not necessarily related to the Maxwell time. Finally, we build a nonequilibrium effective action using the in-in formalism defined on the Schwinger-Keldysh contour, that further supports the emerging picture. In summary, our work suggests that the fundamental difference between solids, fluids, and glasses has to be identified with the associated generalized higher-form global symmetries and their topological structure, and that the Burgers vector for the displacement fields serves as a suitable topological order parameter distinguishing the solid (ordered) phase and the amorphous ones (fluids, glasses).

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  • Received 21 September 2021
  • Accepted 12 January 2022

DOI:https://doi.org/10.1103/PhysRevE.105.024602

©2022 American Physical Society

Physics Subject Headings (PhySH)

Statistical Physics & Thermodynamics

Authors & Affiliations

Matteo Baggioli1,2,*, Michael Landry3,†, and Alessio Zaccone4,5,‡

  • 1Wilczek Quantum Center, School of Physics and Astronomy, Shanghai Jiao Tong University, Shanghai 200240, China
  • 2Shanghai Research Center for Quantum Sciences, Shanghai 201315, China
  • 3Department of Physics, Center for Theoretical Physics, Columbia University, 538 West 120th Street, New York, New York 10027, USA
  • 4Department of Physics “A. Pontremoli,” University of Milan, via Celoria 16, 20133 Milan, Italy
  • 5Cavendish Laboratory, University of Cambridge, J. J. Thomson Avenue, CB30HE Cambridge, United Kingdom

  • *b.matteo@sjtu.edu.cn
  • ml2999@columbia.edu
  • alessio.zaccone@unimi.it

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Issue

Vol. 105, Iss. 2 — February 2022

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