Abstract
NMR experiments have been performed on a series of and electron-doped ceramics. A detailed analysis of the NMR spectra from pristine conclusively shows that the Mo hyperfine field is mainly due to atomic Mo magnetic moments. No contribution of transferred hyperfine field has been observed, confirming the absence of s electrons in the conduction band. Upon La doping, the NMR frequency (hyperfine field) gradually increases, proving that the concentration of spin-polarized electrons at a Mo ion is enhanced by the La substitution. A simple linear correlation between a magnetic moment at Mo sites and the Curie temperature of the system has been found. Implications for understanding the electronic structure and the ferromagnetic coupling in these systems are underlined.
- Received 14 October 2003
DOI:https://doi.org/10.1103/PhysRevB.69.100407
©2004 American Physical Society