In this paper we present a detailed photoemission study of the K/Si(111)7×7 and K/Si(111)(√3 × √3 )R30°-B interfaces. Angle-resolved valence-band spectroscopy reveals the presence of an almost dispersionless interface state below ${\mathit{E}}_{\mathit{F}}$. Both interfaces are clearly nonmetallic at room-temperature saturation coverage. We critically address the issues of charge transfer and Fermi-level pinning by a detailed analysis of the K 3p and Si 2p core-level spectra. We conclude that, up to saturation coverage, correlation effects determine the electronic properties of these interfaces. Metallization occurs during the development of the second layer at cryogenic temperatures.

• Received 31 March 1993

DOI:https://doi.org/10.1103/PhysRevB.48.8119