Abstract
Vacancy-assisted tracer diffusion in a multicomponent kinetic alloy consisting of atoms with hopping rate (where , etc.) and vacancies (where ) distributed randomly over a regular -dimensional (where ) hypercubic, or close-packed, lattice of sites is analyzed through a self-consistent renormalization of a recent theory of Tahir-Kheli and Elliott combined with a generalization of concepts introduced by Manning. The result for the tracer-diffusion correlation factor is the following: , where is the tracer-hopping rate, is a generalized effective vacancy escape frequency, , where is an effective hopping rate of the background atoms averaged with a weighting factor proportional to and , i.e., and . For a single-component alloy, with particle concentration , , and vacancy concentration our theory provides an excellent overall description of the correlation factor as long as . Indeed, even for , the calculated results agree with the Monte Carlo estimates, except in the immediate vicinity of the percolation threshold, , which is located self-consistently to an accuracy of the order .
- Received 4 April 1983
DOI:https://doi.org/10.1103/PhysRevB.28.3049
©1983 American Physical Society