Theoretical study of angular-resolved two-photon ionization of H2

Ph. V. Demekhin, B. M. Lagutin, and I. D. Petrov
Phys. Rev. A 85, 023416 – Published 21 February 2012

Abstract

Cross sections and angular distribution parameters of electrons ejected via two-photon ionization of the hydrogen molecule by linearly and circularly polarized light are computed in the exciting-photon energy range of 8–14 eV, which covers the first four optical resonant states of the molecule. Photoelectron partial waves in the continuous spectrum are obtained within the single center method in precise numerical potential of the molecular ion field. The correlation function technique is used to calculate the two-photon transition matrix element. The presently computed angular-resolved spectra are in good agreement with the theoretical results available for the photon energy of 8.854 eV and can be considered as reliable predictions in the respective energy range.

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  • Received 17 January 2012

DOI:https://doi.org/10.1103/PhysRevA.85.023416

©2012 American Physical Society

Authors & Affiliations

Ph. V. Demekhin1,*, B. M. Lagutin2, and I. D. Petrov2

  • 1Theoretische Chemie, Physikalisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 229, DE-69120 Heidelberg, Germany
  • 2Rostov State Transport University, Narodnogo Opolcheniya Square 2, 344038 Rostov-on-Don, Russia

  • *philipp.demekhin@pci.uni-heidelberg.de

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Vol. 85, Iss. 2 — February 2012

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